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"Why do I have this relationship with France?" Madge asked the crowd of around 1,500 invite-only spectators.
"I'm always drawn to working with French people — and frenching French people! Vive la France!," Madonna added.
The big smooch immediately brought back memories of the infamous liplock with Britney Spears at the 2003 MTV Video Music Awards.
Speaking about how she explained the Britney kiss to her daughter Lourdes, Madonna once told Out magazine: "I am the mommy pop star and she is the baby pop star. I am kissing her to pass my energy on to her."
Enjoy the pictures from Madonna's performance last night